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T-03MATERIAL MARKING GUIDE

Which process
for which material.

A working reference for specifying laser marks on drawings. For each common substrate: the process we reach for first, what the mark looks like, expected contrast, Data Matrix readability, and the notes that usually decide the quote.

SUMMARY TABLE
MaterialPrimary processAlsoContrastData Matrix
Stainless steelAnnealEtch · Engrave · ColorHighExcellent
TitaniumAnnealColor · EtchHighExcellent
Aluminum, bareEtchEngrave · AnnealLow–MediumGood
Aluminum, anodizedAblateEngraveHighExcellent
Carbon and alloy steelEtchAnneal · EngraveHighGood
Tool steelEngraveEtch · AnnealHighGood
Brass, bronze, copperEngraveEtchMediumFair
Engineering plasticsFoam / carbonizeEtchVariableDepends on grade
Coated and painted partsAblateEtchHighExcellent
Ceramics and glassEtchEngraveMediumFair
Laser-markable labels and tag stockAblateAnnealHighExcellent
PROCESS DEFINITIONS
Anneal
Heats the surface below melting to form a dark oxide layer. No material removal, no burr, corrosion resistance preserved. Metals only.
Etch
Light surface melt and re-solidification producing a frosted or discolored mark a few microns deep.
Engrave
Repeated passes remove material to a controlled depth, producing a recessed mark or stepped geometry.
Ablate
Removes a coating, anodize dye, or top layer to expose a contrasting substrate.
Color
MOPA pulse-width control grows an oxide film of specific thickness, producing interference colors on stainless and titanium.
Foam / carbonize
Plastics: localized heating either foams the polymer (light mark) or carbonizes it (dark mark), depending on resin and colorant.
01MATERIAL DETAIL
01

Stainless steel

303, 304, 316/316L, 17-4 PH, 15-5 PH, 410, 420, 440C

Primary
Anneal
Contrast
High
Data Matrix
Excellent

Black oxide anneal with no measurable surface removal; etched marks read gray to white.

  • Annealing keeps the surface intact, which is why it is the default for medical instruments and implants.
  • Anneal marks survive passivation (ASTM A967 / AMS 2700) when the oxide layer is fully formed. We verify post-passivation on request.
  • MOPA pulse control enables stable color marking (blue, gold, bronze) for branding or color-coded parts.

Typical: Surgical instruments, implants, fasteners, valve bodies, food-grade components

02

Titanium

CP Grades 1–4, Ti-6Al-4V (Grade 5), Ti-6Al-4V ELI (Grade 23)

Primary
Anneal
Contrast
High
Data Matrix
Excellent

Dark gray to black anneal; strong interference colors are easy to produce.

  • Titanium oxidizes readily, so annealed marks are dark and high-contrast at modest energy.
  • Avoid deep engraving on fatigue-critical or flight hardware unless the drawing permits it; annealing is non-intrusive.
  • Color marking is common for orthopedic instrument sets and size coding.

Typical: Orthopedic implants and instruments, aerospace brackets, fasteners, UID plates

03

Aluminum, bare

6061-T6, 7075-T6, 2024, 5052, cast A356 / 380

Primary
Etch
Contrast
Low–Medium
Data Matrix
Good

Light gray to white frosted etch; dark marks are achievable with tuned MOPA parameters but are lower contrast than on steel.

  • Bare aluminum does not form a dark oxide the way steel does. For maximum contrast, anodize first and ablate.
  • Deep engraving works well; fill with paint or epoxy when a permanent dark mark is required on bare stock.
  • Cast alloys show porosity in the mark; expect grade variation on rough castings.

Typical: Machined housings, fixtures, tooling, brackets, heat sinks

04

Aluminum, anodized

Type II and Type III (hardcoat) anodize on any wrought alloy

Primary
Ablate
Contrast
High
Data Matrix
Excellent

Bright white or silver mark where the dye layer is removed, on a colored or black background.

  • Black or dark anodize gives the highest-contrast Data Matrix of any common substrate.
  • Ablation removes the dye, not the anodic layer; corrosion resistance is largely preserved on Type II. Hardcoat may show a slight step.
  • Clear anodize marks poorly; specify a colored anodize when marking is planned.

Typical: Nameplates, control panels, enclosures, optical and electronic housings

05

Carbon and alloy steel

1018, 1045, 4140, 4340, 8620, spring steels

Primary
Etch
Contrast
High
Data Matrix
Good

Dark gray to black etch or anneal; deep engraving reads as a sharp recessed line.

  • Marks readily. Engraved regions lose any plating or black oxide and may rust; specify post-mark coating if the part is not otherwise protected.
  • Heat-treated surfaces mark fine; check hardness requirements before deep engraving on case-hardened parts.

Typical: Shafts, gears, weldments, tooling, fixtures, structural hardware

06

Tool steel

A2, D2, S7, H13, O1, M2

Primary
Engrave
Contrast
High
Data Matrix
Good

Crisp engraving for cavity and die identification; surface etch for tool numbers and heat lot.

  • Deep engraving is typically preferred so identification survives regrinding and polishing.
  • Multi-pass engraving handles stepped depths for cavity numbering and date wheels.

Typical: Molds, dies, punches, cutting tools, gauges

07

Brass, bronze, copper

C360, C260, C544, C110 copper, beryllium copper

Primary
Engrave
Contrast
Medium
Data Matrix
Fair

Reflective substrates; marks read as a matte recess or a darker oxidized etch depending on parameters.

  • High reflectivity and conductivity at 1064 nm mean higher energy and slower speeds than steel.
  • Pure copper is the hardest of the group; brass and bronze mark reliably.
  • Paint fill after engraving is common for legible nameplates.

Typical: Electrical hardware, plumbing and valve components, plaques, bushings

08

Engineering plastics

PEEK, ABS, PC, PA (nylon), POM (Delrin), PP, PE, PVC, laser-additive grades

Primary
Foam / carbonize
Contrast
Variable
Data Matrix
Depends on grade

Dark carbonized mark on light resins or a light foamed mark on dark resins. Highly grade-dependent.

  • PEEK, ABS, and PC mark well with a fiber laser. Natural POM, PP, and PE respond poorly without a laser-marking additive.
  • Glass-filled grades mark more consistently than unfilled.
  • Send a sample coupon before releasing a marked-plastic drawing; results vary by colorant and filler.

Typical: Medical device housings, connectors, fluid handling, consumer-durable parts

09

Coated and painted parts

Powder coat, e-coat, wet paint, black oxide, PVD, chem-film

Primary
Ablate
Contrast
High
Data Matrix
Excellent

Coating removed to expose the substrate; contrast set by the coating color versus the base metal.

  • Ablation is selective; the substrate is generally untouched. On steel, the exposed window may need a clear coat.
  • Thick powder coat produces a visible step; thin e-coat and PVD give the cleanest edge.

Typical: Enclosures, panels, brackets, consumer hardware, rating labels

10

Ceramics and glass

Alumina (Al₂O₃), zirconia, silicon nitride, borosilicate

Primary
Etch
Contrast
Medium
Data Matrix
Fair

Dark gray mark on alumina and zirconia; frosted surface mark on glass.

  • Technical ceramics mark well with a fiber laser. Glass is marginal at 1064 nm and is quoted case by case.
  • Micro-cracking risk on thin sections; test on a sample.

Typical: Insulators, substrates, wear components, lab hardware

11

Laser-markable labels and tag stock

Tesa 6930 / 6973 polyacrylic, anodized aluminum tag stock, stainless nameplates

Primary
Ablate
Contrast
High
Data Matrix
Excellent

White-on-black (polyacrylic) or black-on-silver (stainless) with a clean edge.

  • Tamper-evident polyacrylic fractures on removal and is UV-stable outdoors.
  • The right choice when the part itself cannot be marked: composites, painted assemblies, purchased equipment.

Typical: Asset tags, equipment nameplates, calibration labels, facility infrastructure

02FREQUENTLY ASKED
Which metals can be laser marked without removing material?

Stainless steel, titanium, and most carbon and alloy steels can be annealed: the fiber laser heats the surface to form a dark oxide layer without cutting into the part. Annealing is the standard for medical instruments, implants, and any component where surface integrity or corrosion resistance matters. Aluminum, brass, and copper do not anneal and are etched or engraved instead.

Do laser marks survive passivation?

Annealed marks on stainless generally survive citric or nitric passivation because the oxide layer is chemically stable. Etched marks can fade if the passivation bath attacks the re-solidified layer. When a part will be passivated after marking, specify annealing and ask for post-passivation verification.

What is the best material for a high-contrast Data Matrix?

Black anodized aluminum and black polyacrylic tag stock produce the highest contrast, followed by annealed stainless and titanium. Bare aluminum, copper, and unfilled plastics are the hardest substrates for reliable 2D code verification.

Can you laser mark bare aluminum with a dark mark?

Partially. A MOPA fiber laser with tuned parameters can produce a dark gray mark on bare aluminum, but contrast is lower than on steel and varies by alloy and surface finish. For consistently dark marks, either anodize the part first or engrave and paint-fill.

Which plastics laser mark well?

PEEK, ABS, polycarbonate, and most glass-filled nylons mark well with a 1064 nm fiber laser. Natural polypropylene, polyethylene, and acetal (Delrin) respond poorly unless they contain a laser-marking additive. We recommend a sample coupon before releasing a drawing that calls for laser marking on plastic.

How do I specify the marking process on a drawing?

Call out the mark content, location, size, and method (for example, "LASER ANNEAL, NO SURFACE REMOVAL" or "LASER ENGRAVE 0.003 IN DEEP"). Reference MIL-STD-130 for UID content and AS9132 for aerospace direct part marking practice. If unsure, send the drawing with an RFQ and we will propose the process.

MATERIAL NOT LISTED?

Send a sample coupon — we’ll dial it in.

Parameters are tuned per substrate and finish. A test piece returns with a marked sample and our recommended process before you commit the drawing.